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engleski
This enzyme belongs to the family of isomerases, specifically those intramolecular oxidoreductases interconverting keto- and enol-groups.
en.wikipedia.org
The mechanism suggests that red light is emitted from the keto form of oxyluciferin, while green light is emitted from the enol form of oxyluciferin.
en.wikipedia.org
When the substituent on the other hand is phenyl (not shown) the phosphite has a preference for reaction with the acyl group leading to an ethyl enol ether.
en.wikipedia.org
By treatment of the glycosylamine with pyridine and acetic anhydride, the imine group rearranges and the intermediate enol, in turn, rearranges to the ketone.
en.wikipedia.org
A decarboxylation reaction forms an excited state of oxyluciferin, which tautomerizes between the keto-enol form.
en.wikipedia.org

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